Spin polarized tunneling in large area mesas of superconducting Bi2Sr2CaCu2O8+d for terahertz emission

Thesis (Master)--Izmir Institute of Technology, Physics, Izmir, 2010Includes bibliographical references (leaves: 70-77)Text in English; Abstract: Turkish and Englishxi, 77 leavesThere is an increasing interest in science and technology of electromagnetic waves in terahertz frequency range (0.1-10 THz) because of their emerging application areas including physics, biology, chemistry, astronomy, medicine etc. The observation on generation of THz radiation emitted from lateral dimension of high temperature superconductor (HTS) Bi2Sr2CaCu2O8+.. (Bi2212) and responses to THz waves increase the importance of these HTSs. Single crystal of HTS Bi2212 forms natural superconductor-insulator-superconductor (SIS) layered junctions, which are called intrinsic Josephson junctions (IJJ). The stacks of IJJs in Bi2212 can be used such a voltage-frequency converter and their large energy gap allows the emissions at THz frequency range. Recently, it has been demonstrated that rectangular IJJ mesa structures of Bi2212 can be used as a source of continuous, coherent and polarized THz radiation. It was shown that all THz emitting mesas are below a certain underdoped level, which has relatively small critical current in contrast to optimally doped and overdoped Bi2212. In this work, rectangular Au/Co/Au/Bi2212 mesa structures with large areas and high thicknesses were fabricated on as-grown Bi2212 single crystals using standard photolithograph and Ar ion beam etching techniques. In order to characterize the mesas, c-axis resistance versus temperature (R-T) and current-voltage (I-V) characteristics were investigated. During I-V characterization, Si composite bolometer was used to detect the emission. We obtained small critical current from as-grown mesas due to injection of spin polarized current. We observed THz emission peak for one of the mesas which has low quasiparticle conductivity and low dissipation due to its small critical current density. It means that the adjustment of doping level can be eliminated for THz emission by the injection of spin polarized current through the c-axes of the asgrown mesas

The fabrication of THz emitting mesas by reactive ion-beam etching of superconducting Bi2212 with multilayer masks

Generation of powerful THz radiation from intrinsic Josephson Junctions (IJJs) of Bi2Sr2CaCu2O8+δ (Bi2212) may require mesas with large lateral dimensions. However, there are difficulties in fabrication of perfect rectangular mesas. The lateral angles of mesas should be close to 90 degrees to obtain IJJs with same planar dimensions for synchronization of IJJs. We patterned Ta/photoresist and photoresist/Ta/photoresist masks on Bi2212 and used selectiveionetchingtoovercomethethickphotoresistlayershading on the lateral dimension of mesa during the ion-beam etching. The reactive ion-beam etchings have been done with ion beams of Ar, N2 and O2, and we have obtained mesas about 1 µm with lateral angle of approximately 50 to 75°, which is better than the mesas fabricated with photoresist mask.TUBITAK (Scientific and Technical Council of Turkey) project No. 108T238

Spin polarized tunneling in large area mesas of superconducting Bi2Sr2CaCu2O8+d for terahertz emission

Thesis (Master)--Izmir Institute of Technology, Physics, Izmir, 2010Includes bibliographical references (leaves: 70-77)Text in English; Abstract: Turkish and Englishxi, 77 leavesThere is an increasing interest in science and technology of electromagnetic waves in terahertz frequency range (0.1-10 THz) because of their emerging application areas including physics, biology, chemistry, astronomy, medicine etc. The observation on generation of THz radiation emitted from lateral dimension of high temperature superconductor (HTS) Bi2Sr2CaCu2O8+.. (Bi2212) and responses to THz waves increase the importance of these HTSs. Single crystal of HTS Bi2212 forms natural superconductor-insulator-superconductor (SIS) layered junctions, which are called intrinsic Josephson junctions (IJJ). The stacks of IJJs in Bi2212 can be used such a voltage-frequency converter and their large energy gap allows the emissions at THz frequency range. Recently, it has been demonstrated that rectangular IJJ mesa structures of Bi2212 can be used as a source of continuous, coherent and polarized THz radiation. It was shown that all THz emitting mesas are below a certain underdoped level, which has relatively small critical current in contrast to optimally doped and overdoped Bi2212. In this work, rectangular Au/Co/Au/Bi2212 mesa structures with large areas and high thicknesses were fabricated on as-grown Bi2212 single crystals using standard photolithograph and Ar ion beam etching techniques. In order to characterize the mesas, c-axis resistance versus temperature (R-T) and current-voltage (I-V) characteristics were investigated. During I-V characterization, Si composite bolometer was used to detect the emission. We obtained small critical current from as-grown mesas due to injection of spin polarized current. We observed THz emission peak for one of the mesas which has low quasiparticle conductivity and low dissipation due to its small critical current density. It means that the adjustment of doping level can be eliminated for THz emission by the injection of spin polarized current through the c-axes of the asgrown mesas

Effect of substrate rotation speed and off-center deposition on the structural, optical, and electrical properties of AZO thin films fabricated by DC magnetron sputtering

In this study, aluminum-doped zinc oxide (AZO) thin films were deposited by DC magnetron sputtering at room temperature. The distance between the substrate and target axis, and substrate rotation speed were varied to get high quality AZO thin films. The influences of these deposition parameters on the structural, optical, and electrical properties of the fabricated films were investigated by X-ray diffraction (XRD), Raman spectroscopy, spectrophotometry, and four-point probe techniques. The overall analysis revealed that both sample position and substrate rotation speed are effective in changing the optical, structural, and electrical properties of the AZO thin films. We further observed that stress in the films can be significantly reduced by off-center deposition and rotating the sample holder during the deposition. An average transmittance above 85% in the visible range and a resistivity of 2.02 × 10-3Ω cm were obtained for the AZO films.TUBITAK (114F341

Fabrication of double mesa structures by E-beam lithography from high temperature superconducting Bi<inf>2</inf>Sr<inf>2</inf>CaCu<inf>2</inf>O<inf>8+δ</inf> (Bi2212) for powerful terahertz emission

30th URSI General Assembly and Scientific Symposium, URSIGASS 2011; Istanbul; Turkey; 13 August 2011 through 20 August 2011We work on a frequency tunable solid state device to meet the needs of continuous, coherent, powerful terahertz emission sources that fill practically important terahertz gap. High temperature superconducting (HTS) coherently oscillating Josephson junctions in Bi2Sr2CaCu 2O8+δ (Bi2212) crystal make this approach very promising. Since doping dependence of Bi2212 is an important parameter, Bi2212 crystals are annealed in vacuum or purified argon gas flow at 425°C. For further processing we pattern both single and double rectangular mesa structures by using electron beam lithography on the cleaved surface of the crystal. Resistance-temperature (R-T), and current-voltage behavior (I-V) measurements achieved. © 2011 IEEE.Scientific and Technical Council of Turkey project no. 110T24

Area dependence and influence of crystal inhomogeneity on superconducting properties of Bi2212 mesa structures

The rapid increase in applications of terahertz waves requires new techniques to obtain continuous wave terahertz sources. Mesa structures fabricated from high-Tc superconductor Bi2Sr2CaCu2O8+δ (Bi2212) single crystal have been observed as an intense, coherent, continuous electromagnetic wave source in the terahertz (THz) frequency region. However, in order to produce coherent radiation with high applicable power, we need large mesa structures that enter a collective electromagnetic state in which their oscillations are largely synchronized in phase. On the other hand, large mesa structures cause a heating problem. In this study, we report on the critical current density dependence of mesa area and the crystal inhomogeneity to understand heating problems in large area mesas for terahertz radiation. Since the doping dependence of Bi2212 is an important parameter, the as-grown Bi2212 crystals were heat-treated at various temperatures under vacuum conditions. We have fabricated triple mesa structures from Bi2212 single crystal using e-beam lithography and argon ion beam etching techniques with same area and with different area on the same chip. We investigated and compared characteristics of triple mesas which are on the same chip and next to each other. In this way, we searched the crystal inhomogeneity in triple mesa structures and studied the critical current density dependence of mesa area to obtain high emission power for the THz radiation. Our experimental results clearly show that the Josephson critical current density is decreasing when the area of mesa is increasing. © 2015 Elsevier Ltd. All rights reserved.TUBITAK (110T248); SANTEZ (1386.STZ.2012-1

DD genotype of ace gene I/D polymorphism is associated in a turkish study population with osteoarthritis

This study was conducted in Turkish osteoarthritis patients to determine the frequency of I/D polymorphism genotypes of angiotensin converting enzyme gene, and to examine the role of this polymorphism in osteoarthritis development. Genomic DNA obtained from 200 persons (135 patients with osteoarthritis and 65 healthy controls) was used in the study. DNA was multiplied by polymerase chain reaction using I and D allele-specific primers. Polymerase chain reaction products were assessed with CCD camera by being exposed to 2% agarose gel electrophoresis. There was statistically significant difference between the groups with respect to genotype distribution (P < 0.001). The D allele frequency was indicated as 69% and I allele was as 31% in the patients, whereas it was 55-45% in the control group. Consequently, in this study, we may assert that ACE gene I/D polymorphism DD genotype determination is significant criteria for identifying patients who are likely to develop osteoarthritis in east population of Turkey

Emission of the THz waves from large area mesas of superconducting Bi 2Sr2CaCu2O8+δ by the injection of spin polarized current

Rectangular Au/Co/Au/Bi2Sr2CaCu2O 8+δ (Bi2212) mesa structures with large areas and high thicknesses were fabricated on as-grown Bi2212 single crystals in order to obtain small critical current from as-grown mesas by the injection of spin polarized current and so eliminate the adjustment of doping level for successful THz emission. We have performed c-axis resistance versus temperature (R-T), current-voltage (I-V) characteristics and bolometer measurements. It is the first time that THz emission has been observed from as-grown mesas due to injection of spin polarized current. © 2013 Elsevier Ltd. All rights reserved

Influence of sulfurization temperature on Cu2ZnSnS4 absorber layer on flexible titanium substrates for thin film solar cells

In this study, the effect of sulfurization temperature on the morphology, composition and structure of Cu2ZnSnS4 (CZTS) thin films grown on titanium (Ti) substrates has been investigated. Since Ti foils are flexible, they were preferred as a substrate. As a result of their flexibility, they allow large area manufacturing and roll-to-roll processes. To understand the effects of sulfurization temperature on the CZTS formation on Ti foils, CZTS films fabricated with various sulfurization temperatures were investigated with several analyses including x-ray diffraction (XRD), scanning electron microscopy (SEM), x-ray photoelectron spectroscopy and Raman scattering. XRD measurements showed a sharp and intense peak coming from the (112) planes of the kesterite type lattice structure (KS), which is strong evidence for good crystallinity. The surface morphologies of our thin films were investigated using SEM. Electron dispersive spectroscopy was also used for the compositional analysis of the thin films. According to these analysis, it is observed that Ti foils were suitable as substrates for the growth of CZTS thin films with desired properties and the sulfurization temperature plays a crucial role for producing good quality CZTS thin films on Ti foil substrates.TUBITAK (114F341